Causes and Solutions of Paint Swelling, Gelation, and Livering During Storage

Introduction: Paint swelling is a serious quality issue during storage, manifesting as significant viscosity increase until becoming thick paste, colloid or hard lumps. This article systematically analyzes the causes of three phenomena – false bodying, gelling and livering – and provides complete solutions covering pigment selection, production processes to storage management.

What is Paint Swelling?

  1. False Bodying: Paint appears thick, flows freely after mechanical stirring, recovers after stopping
  2. Gelling: Paint changes from liquid to unusable solid/semi-solid, becoming gelatinous
  3. Livering: Paint becomes hard rubber-like, resembling liver, requires excessive dilution or remains unusable

Common Causes of Paint Swelling

  1. Formulation Factors:
    • False Bodying: High pigment content paints containing talc, zinc oxide, lithopone, red lead
    • Pigment-Resin Reaction: Gold powder, chrome yellow with nitrocellulose; saponification of high acid value paints with basic pigments
    • Charge Incompatibility: Positive charged colloidal binders with negative charged pigments
  2. Packaging and Storage:
    • Inadequate sealing or underfilling, solvent evaporation
    • Moisture ingress promoting livering and gelling
    • Excessive storage temperature

Solutions to Prevent and Fix Paint Swelling

  1. Different Phenomenon Treatments:
    • False Bodying: Strong stirring with wooden stick
    • Livering: Add thinner for primer use if slight; downgrade or scrap if severe
    • Gelling: Mechanical stirring or add少量organic acid; for tung oil, add 3% glycerol with heating
  2. Formulation and Process Optimization:
    • Avoid basic pigments, use lithopone, titanium dioxide, antimony oxide
    • Use immediately after preparation for red lead, etc.
    • Avoid moisture ingress, avoid production under high humidity
  3. Storage Management:
    • Keep containers sealed, use within 2-3 days after opening
    • Store at 15-25℃, avoid sunlight, radiators or stoves

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